Clay–Organic Hybrid Films Exhibiting Reversible Fluorescent Color Switching Induced by Swelling and Drying of a Clay Mineral
M. Tominaga, Y. Oniki, S. Mochida, K. Kasatani, S. Tani, Y. Suzuki, J. Kawamata
J. Phys. Chem. C, 2016, 120, 23813–23822
DOI: 10.1021/acs.jpcc.6b07537

Abstruct: The interlayer space of clays is an interesting microenvironment to control the properties of included organic materials. In this study, chromic hybrid films consisting of synthetic saponite (SSA) and fluorescent organic molecules with planar π-conjugated systems were fabricated. The hybrid films exhibited reversible fluorescence color switching induced by swelling and drying, which caused the gallery height of SSA to change. Ultraviolet–visible absorption, steady-state and time-resolved fluorescence measurements of the hybrid films strongly suggested that the organic molecules formed an excimer in the swollen interlayer space of SSA, while they were a monomer in the dried interlayer space. The different emission wavelengths of the excimer and monomer resulted in the fluorescence color switching of the hybrid films. The reversibility of the color switching was maintained for at least 50 cycles with no change of fluorescence maxima. These chromic hybrid films represent a novel approach to obtain color switching.